Tags

Related Posts

Share This

formaldehyde gas sds

SARA: Section 355 (extremely hazardous substances): 50-00-0 formaldehyde. During the 1970s, urea-formaldehyde foam insulation (UFFI) was used in many homes. 2 (H225); … For personal protection see section 8. Consult an expert! /Formaldehyde/ /Formalin (as formaldehyde)/, NIOSH usually recommends that occupational exposures to carcinogens be limited to the lowest feasible concentration. P271 Use only outdoors or in a well-ventilated area. Eye Contact: Vapors cause irritation to the eyes with redness, pain, and blurred visi on. Also, a positive association has been observed between exposure to formaldehyde and sinonasal cancer. 5.3. Effects in women include menstrual disorders and secondary sterility. The authors and Working Group felt that this study needed to be replicated. Wear dust mask when handling large quantities. Wear impervious clothing. Remove all ignition sources. Formaldehyde: off-gas : 200-001-8: Section 3 - Hazards Identification EMERGENCY OVERVIEW. Formaldehyde (as urea formaldehyde foam) was extensively used as an insulating material until 1982 when it was banned by the U.S. Consumer Product Safety Commission. R40- Limited evidence of a carcinogenic effect. (USCG, 1999). Water spray may be used to flush spills away from exposures and to dilute spills to nonflammable mixtures. When heated, irritant formaldehyde gas evolved from solution. Ingestion. Refer immediately for medical attention. Exposure Routes: inhalation, skin and/or eye contact Symptoms: Irritation eyes, nose, throat, respiratory system; lacrimation (discharge of tears); cough; wheezing; [potential occupational carcinogen] Target Organs: Eyes, respiratory system (NIOSH, 2016), The probable oral lethal dose for humans is 0.5-5 g/kg, or between 1 ounce and 1 pint for a 150 pound person. The Koc of formaldehyde is estimated as 8(SRC), using a log Kow of 0.35(1) and a regression-derived equation(2). Vapors may form explosive mixtures with air. Keep container tightly closed. !#™kîºðp ×]„‘‰åÚt!Ô²#¡óݬ¡eºh­¼íF¨¥ìHh|•°-Bž³ÄEæ1‰¬ú«7\Æ(§’¥½¯ c“‹DÖӋu–­ï.©}ŽÒ{.˜œ'Vç. Gas is stable in absence of water. stream Acute -- below 1 ppm, odor perceptible to most. Handle with gloves. According to a classification scheme(3), this estimated Koc value suggests that formaldehyde is expected to have very high mobility in soil(SRC). Commercial formaldehyde-alcohol solutions are stable. Remove contact lenses, if present and easy to do. 1B (H350) Concentration: < 5% Component: Methanol CAS No: 67-56-1 EC No: 200-659-6 Index No: 603-001 -00-x Registration No: 01-2119433307 -44-xxxx Classification: Flam. P302+P352 IF ON SKIN: Wash with plenty of water/... P312 Call a POISON CENTER/doctor/\u2026if you feel unwell. endobj Acute exposure to formaldehyde can have a corrosive effect on the respiratory tract, gastrointestinal system, and skin. <> Evacuate personnel to safe areas. May generate flammable and/or toxic gases in combination with azo, diazo compounds, dithiocarbamates, nitrides, and strong reducing agents. b. Administer intravenous saline or other crystalloids to replace fluid losses caused by gastroenteritis. Remove gas with fine water spray. A person conducting a business or undertaking (PCBU) must correctly labelhazardous chemicals used, handled or stored at the workplace, including containers and pipework. /From table/. Harmful if inhaled. 77, No. Reacts with nitrogen oxides at about 180; the reaction becomes explosive. endobj Supplier . In laboratories, the gas is more commonly dissolved in water and used as an aqueous solution called formalin. T - Toxic. Wear self-contained breathing apparatus for firefighting if necessary. It can cause irreversible eye damage in instances of severe overexposure. Vapors may cause dizziness or suffocation. Formaldehyde, Lab Grade Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com SECTION 1: Identification of the substance/mixture and of the supplier Product name: Formaldehyde, Lab Grade Manufacturer/Supplier Trade name: Manufacturer/Supplier Article number: S25329 Recommended uses of the product and restrictions on use: Manufacturer Details: … Metals such as platinium, copper, chromia, and alumina also catalyze the formation of methanol, methylformate, formic acid, carbon dioxide, and methane. Hazard class: Flammable liquids (Category 3). It has virtually no activity for ethanol oxidation, but exhibits high activity for oxidation of long-chain primary alcohols and for oxidation of S-hydroxymethyl-glutathione, a spontaneous adduct between formaldehyde and glutathione. Workers can inhale formaldehyde as a gas or vapour or absorb it through the skin as a liquid. purest form, formaldehyde is a colorless, highly toxic and flammable gas with the chemical formula HCHO or CH 2 O. Most vapors are heavier than air. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. There is sufficient evidence in humans for the carcinogenicity of formaldehyde. May be harmful if swallowed or absorbed through the skin. 5.2. Solutions splashed in eyes have caused injuries ranging from severe, permanent corneal opacification and loss of vision to minor discomfort. Product identifier . P201 Obtain special instructions before use. Contact with substance may cause severe burns to skin and eyes. Refer immediately for medical attention. The main products of decomposition are carbon monoxide and hydrogen. Formaldehyde causes cancer of the nasopharynx and leukaemia. Formaldehyde in aqueous effluent was degraded by activated sludge and sewage in 48-72 hr(3-6). 1.1. In addition, formaldehyde may interact with humic substances in soil(5) resulting in decreased mobility. Containers may explode when heated. LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA T 412-826-5230 - F 724-473-0647 info@labchem.com - … Suppliers of a hazardous chemical to a workplace must provide current safety data sheets. /Pure formaldehyde/, Lower flammable limit: 7.0% by volume; Upper flammable limit: 73% by volume, In water:soluble, > 100\u2009g/100 ml\uff0820\u2009\u00b0C\uff09, ADR/RID: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, IMDG: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, IATA: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, Oral: LD50 Rat oral 100 mg/kg /SRP: percent solution not specified/, Inhalation: LC50 Rat inhalation 0.82 mg/L (1/2 hour), Dermal: LD50 Rabbit percutaneous 270 mg/kg /Formalin/, Toxicity to fish: LC50; Species: Oncorhynchus mykiss (Rainbow trout) weight 0.63 g; Conditions: static; Concentration: 118 ppm for 96 hr (95% confidence limit: 99.7-140 ppm) /37% AI formulated product, Toxicity to daphnia and other aquatic invertebrates: EC50; Species: Daphnia magna (Water Flea) age <24 hr; Conditions: freshwater, static; Concentration: 14600 ug/L for 48 hr (95% confidence interval: 11300-18000 ug/L); Effect: intoxication, immobilization /37% purity, Toxicity to algae: EC50; Species: Scenedesmus subspicatus (Green Algae); Conditions: freshwater, static; Concentration: 211000 ug/L for 49-79 min; Effect: population, decreased photosynthesis /formulation, Toxicity to microorganisms: no data available, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. Rinse mouth. Use of the substance/mixture : For laboratory and manufacturing us e only. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. SAFETY DATA SHEET GHS product identifier Other means of identification Product type Section 1. A study of hospital equipment sterilizing workers did not report an association between formaldehyde exposure and increased spontaneous abortions. Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. may react violently with strong oxidizing agents (hydrogen peroxide, performic acid, perchloric acid in the presence of aniline, potassium permanganate, nitromethane). It is made of 37% formaldehyde and impurities such as methanol, small amounts of formic acid, aldehydes and ketones. Use D-Formalizer® pads or F.C.G.® Formaldehyde Control Granules to reduce formaldehyde exposure. .sds-ghs .header, .sds-ghs .content { font-family: 'times_new_roman', 'Times New Roman', sans-serif; } .avoid-page-break-inside { page-break-inside:avoid; } .sds-ghs h1, .sds-ghs h2, .sds-ghs h3, .sds-ghs h4, .sds-ghs h5, .sds-ghs h6 { font-weight: bold; } .sds-ghs h1 { text-align: left; font-size: 2em; margin: 0.67em 0; } .sds-ghs h2 { text-align: left; color: grey; font-size: 1.2em; margin: 0.83em 0; } .sds-ghs h3 { font-size: 1.17em; margin: 10px 0; } .sds-ghs h4 { /*text-align:center;*/ font-size: 1em; margin: 10px 0; } .sds-ghs h5 { font-style: italic; color: grey; font-size: 0.83em; margin: 10px 0; } .sds-ghs p { /*border: 1px solid blue;*/ color: black; line-height: 1; margin-bottom: 5px; } .sds-ghs hr { /*border: 1px solid blue;*/ color: black; margin: 0.5em 0; } .sds-ghs table { width: 100%; border-collapse: collapse; } .sds-ghs table td, .sds-ghs table th { border: 1px solid black; text-align: center; line-height: 1.5em; } .sds-ghs .subtitle { font-size: 12px; color: grey; text-align: right; } .sds-ghs .table-border-none th, .sds-ghs .table-border-none td { border: none; text-align: left; vertical-align: top; line-height: 1; } .sds-ghs .width-pc-70 { width: 70%; } .sds-ghs .width-pc-30 { width: 30%; } .sds-ghs .width-100 { width: 100px; } .sds-ghs .title-number { width: 50px; float: left; display: inline-block; } .sds-ghs .title-content { padding-left: 50px; display: block; } .sds-ghs .title { margin-right: -50px; border-top: 1px solid; } .sds-ghs .content { margin-left: 50px; margin-right: 50px; } .sds-ghs .m-t { margin-top: 15px; } .sds-ghs .text-left { text-align: left; } .sds-ghs h3 { margin-left: -50px; } .sds-ghs h3:before { clear: both; content: ''; }, H314 Causes severe skin burns and eye damage, H341 Suspected of causing genetic defects. Rinse skin with plenty of water or shower. However, possible confounding factors were not evaluated in this study. Ensure airborne concentrations of formaldehyde do not exceed published exposure limits. : A registration number is not available for this substance as the substance or its uses are … P301+P330+P331 IF SWALLOWED: Rinse mouth. Can react with hydrogen chloride or other inorganic chlorides to form bis-chloromethylether (BCME), a known carcinogen. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Vapors may travel to source of ignition and flash back. Minimum storage temperature to prevent polymerization range from 83 deg F for 37% formaldehyde containing 0.05% methyl alcohol to 29 deg F for formaldehyde containing 15% methyl alcohol. May be ignited by heat, sparks or flames. P363 Wash contaminated clothing before reuse. … Compound will polymerize with active organic materials such as phenol. Rinse skin with water [or shower]. P321 Specific treatment (see ... on this label). Avoid fluid overload in patients with inhalation exposure because of the risk of pulmonary edema. General description Formaldehyde (formalin) is produced by oxidation of methanol. Maintain open airway and assist ventilation if necessary. formaldehyde and carbon oxides). 3 0 obj May cause allergic respiratory and skin reaction. DOWNLOAD MSDS (PDF) | Search MSDS currently available for download bioWORLD offers Formaldehyde (4%) in PBS for your research at low price. Use fluorocarbon water spray, Cellosize and Hycar to diminish vapors. Homes in which UFFI was installed many years ago are not likely to have high formaldehyde levels now. Evacuate danger area! : 605-001-00-5 REACH No. 1.3. Avoid dust formation. Treat bronchospasm and pulmonary edema if they occur. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 11/15/2013 Revision date: 02/27/2014 Supersedes: 11/15/2013 Version: 1.1 03/05/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking . Continue rinsing. Component: Formaldehyde CAS No: 50-00-0 EC No: 200-001-8 Index No: 605-001 -00-5 Classification: Acute Tox. P272 Contaminated work clothing should not be allowed out of the workplace. (ERG, 2016), Vapor or dust irritates eyes, mucous membranes, and skin; may cause dermatitis. R23/24/25- Toxic by inhalation, in contact with skin and if swallowed. Liq. Vapour is heavier than air and is an explosion hazard. Safety Data Sheet Sodium Formaldehyde Bisulphite Solution SDS 26/7 Page n. 3 of 8 None in particular. Evacuate area. Avoid breathing dust. Runoff to sewer may create fire or explosion hazard. P361+P364 Take off immediately all contaminated clothing and wash it before reuse. endobj P333+P313 If skin irritation or rash occurs: Get medical advice/attention. Seek medical attention if you feel unwell. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. 1 (H317), Muta. Very few human studies have been done on the adverse reproductive effects from exposure to Formaldehyde. CERCLA: Formaldehyde 50-00-0: RQ = 100 lbs (45.4 Kg). read more → Formaldehyde in PBS is a common fixitive reagent for histology in light microscopy and EM applications.... read more → Identification::: Supplier's details : Nonflammable Gas Mixture: Formaldehyde 1ppb-999ppm / Nitrogen 99.9001-99. But few homes are now insulated with UFFI. Fire will produce irritating, corrosive and/or toxic gases. Show this safety data sheet to the doctor in attendance. Manufacturers and importers of formaldehyde/formalin need to ensure that hazardous chemicals are labelled and that safety data sheets are prepared and provided. Rinse with plenty of water (remove contact lenses if easily possible). Formaldehyde is produced in large quantities industrially. Wash hands before breaks and at the end of workday. Artificial respiration may be needed. Use water to keep fire exposed containers cool. Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 5.2 SDS Revision Date: 7/20/2018 5. The main products are carbon monoxide and hydrogen. 1 0 obj SDS # :012612 Airgas USA, LLC … Formaldehyde is used predominantly as a chemical intermediate. E-mail (competent person) SDS@vwr.com 1.4 Emergency phone number Telephone +44 (0) 1270 502894 (CareChem24) 2 / 14 SECTION 2: Hazard identification 2.1 Classification of the substance or mixture 2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP] Hazard classes and hazard categories Hazard statements Acute toxicity, category 3, oral, dermal and inhalation … Administer supplemental oxygen, and observe for at least 4 to 6 hours. P260 Do not breathe dust/fume/gas/mist/vapours/spray. Sodium carbonate, ammonium hydroxide, or sodium sulfite can neutralize the spill. Experiments performed on a variety of fish and shrimp showed no bioconcentration of formaldehyde(4,5). 2-3 ppm, mild tingling of eyes. For industry use only. An estimated BCF of 3 was calculated for formaldehyde(SRC), using a log Kow of 0.35(1) and a regression-derived equation(2). 1.2. Cat. Incompatible with amines, azo compounds, dithiocarbamates, alkali and alkaline earth metals, nitrides, nitro compounds, unsaturated aliphatics and sulfides, organic peroxides, oxidizing agents, and reducing agents. Also reacts violently with perchloric acid-aniline, performic acid, nitromethane, magnesium carbonate, and hydrogen peroxide. Formaldehyde gas adsorbs on clay minerals to a degree at high gas concentrations which is an important quality in its use as a soil fumigant(4). Polymerization reaction with phenol may develop sudden destructive pressure [Bretherick, 5th ed., 1995, p.168]. P280 Wear protective gloves/protective clothing/eye protection/face protection. 4-5 ppm, increased discomfort, mild lacrimation. An increased incidence of menstrual disorders were observed in female workers using urea-formaldehyde resins. Product name : Formaldehyde, 10% v/v, Buffered Product code : LC14670 . <>>> Avoid contact with skin and eyes. Formaldehyde is carcinogenic to humans (Group 1). Vapor explosion hazard indoors, outdoors or in sewers. Gas. P202 Do not handle until all safety precautions have been read and understood. When heated, irritant formaldehyde gas evolved from solution. Formaldehyde Solution Flinn Scientific, Inc. P.O. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Turn off gas at source if possible. Keep upwind to avoid inhalation of gases, vapours, fumes and smoke. Causes eye, skin, and respiratory tract irritation. Nonflammable Gas Mixture: Formaldehyde 1ppb-999ppm / Nitrogen 99.9001-99.9999% Not available. Recommended use and restrictions on use . C - Corrosive. Hazardous polymerization may occur. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). 1B (H314), Skin Sens. Many liquids are lighter than water. Formaldehyde (/ f ə r ˈ m æ l d ə h aɪ d / fer-mal-duh-hahyd, also / f ɔːr ˈ m æ l d ə h aɪ d / fawr-) (systematic name methanal) is a naturally occurring organic compound with the formula CH 2 O (H−CHO). California … Large Spill and Leak: Stop leak if it is safe to do so. P362+P364 Take off contaminated clothing and wash it before reuse. Synonym :Monoxide; Flue gas; Carbon oxide; carbonic oxide; Monoxide of carbon; Carbon monooxide SDS # :001014 Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 24-hour telephone :1-866-734-3438 Section 2. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Do not discharge to sewer systems. SECTION 2 — HAZARDS IDENTIFICATION. (EPA, 1998), Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]: May cause toxic effects if inhaled or ingested/swallowed. 10 ppm, profuse lacrimation; can be withstood only for few minutes. For precautions see section 2.2. Some may be transported hot. Carc. (Amines) exothermic reaction, (AZO cmpd) exothermic reaction giving off nitrogen gas, (caustics) heat generation and violent polymerization, (dithiocarbamates) formation of flammable gasses and toxic fumes, formation of carbon disulfide may result, (alkali and alkaline earth metals) heat generation and formation of flammable hydrogen gas, (nitrides) heat generation, formation of flammable ammonia gas and violent polymerization, (nitro compd) heat generation, (unsaturated aliphatics and sulfides) heat generation, (organic peroxides) violent reaction, (oxidizing agents) heat generation, fire, and decomposition, (reducing agents) heat generation and formation of flammable gasses. Formaldehyde resins are used as adhesives and binders in many different industries that produce wood products, pulp and paper, synthetic fibres, plastics and coating and textiles. The Working Group was not in full agreement on the evaluation of formaldehyde causing leukaemias in humans, with a small majority viewing the evidence as sufficient of carcinogenicity and the minority viewing the evidence as limited. Gloves must be inspected prior to use. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 2. 4 0 obj P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/\u2026. /Formaldehyde/ /Formalin (as formaldehyde)/. Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. High formaldehyde concentration or methanol content lowers flash point. There is sufficient evidence in experimental animals for the carcinogenicity of formaldehyde. P310 Immediately call a POISON CENTER/doctor/\u2026. GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name Formaldehyde solution, 36.5: -38% Product Number : F8775 Brand : Sigma Index-No. Emergency and supportive measures: 1. Reacts with peroxide, nitrogen oxide, and performic acid causing explosions. Higher concentrations or splashes may cause irreversible eye damage. Contact causes white discoloration, smarting, cra cking and scaling. Treat coma and shock if they occur. Explosion hazard: when aqueous formaldehyde solutions are heated above their flash points, a potential for explosion hazard exists. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. Advice for firefighters Use suitable breathing apparatus. Fresh air, rest. May react with bases (sodium hydroxide, potassium hydroxide, ammonia), and with nitrogen dioxide (explosive reaction around 180\u00b0C). Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. 10-20 ppm, breathing difficult, cough, severe burning of nose and throat. Safety glasses with side-shields conforming to EN166. Methanol 67-56-1 200-659-6 1.00 % v/v F - Highly flammable. Developmental effects, such as birth defects, have not been observed in animal studies with formaldehyde. Formalin solutions typically use up to 15% methanol as a stabilizer. 2 0 obj If dry, it can be charged electrostatically by swirling, pneumatic transport, pouring, etc.FORMALDEHYDE (ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.) Advice for fire-fighters: Self-contained breathing apparatus and protective clothing. Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Some may burn but none ignite readily. Metals such as platinum, copper, chromia, and alumina also catalyze the formation of methanol, methylformate, formic acid, carbon dioxide, and methane. SDS #: 352. Odour Threshold: 0,05 – 0,125 ppm (Formaldehyde) pH: 2,8 – 4,0 at 20°C Melting point: < -15°C Boiling point/boiling range: 93-96°C at 1.013 hPa Flash point: 62°C Method: c.c Evaporation rate: No information available Flammability (solid, gas): No information available Also reacts violently with perchloric acid-aniline, performic acid, nitromethane, magnesium carbonate, and hydrogen peroxide. Formaldehyde, 37% w/w Safety Data Sheet according to Federal Register / Vol. <> pH 2.8 – 4.0 (25 degrees Celsius) (37% solution) Odour threshold 0.8 – 1ppm Percent volatile … MAJOR HEALTH HAZARDS:potentially fatal if inhaled, harmful on contact with the skin or swallowed, respiratory tract burns, skin burns, eye burns, allergic reactions, cancer hazard (in humans) Formaldehyde –urea resin is used as an insulating material in building construction. Wash and dry hands. Very reactive, combines readily with many substances, 40% solution is powerful reducing agent. Flash Point: 70 deg C. Warning! P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Skin -- primary irritation from strong solutions, gas. Cool. FIREFIGHTING MEASURES 5.1 Fire & Explosion Hazards: Will not burn, but high heat, may release formaldehyde gas which will increase the health hazards. Delayed -- sensitization dermatitis. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. Formaldehyde Formaldehyde (HCHO) CAS 50-00-0; UN 1198, UN 2209 (formalin) ... • Formaldehyde is a colorless, highly toxic, and flammable gas at room temperature that is slightly heavier than air. Formaldehyde exposure can also happen in offices and newly constructed homes via off-gas from wood products, paints and finishes, and cigarette smoke. Recommended Exposure Limit: 10 Hour Time-Weighted Average: 0.016 ppm. It also has minor uses in agriculture, as an analytical reagent, in concrete and plaster additives, cosmetics, disinfectants, fumigants, photography, and wood preservation. c. Treat metabolic acidosis with sodium bicarbonate. 3 Xi - Irritant. Can react with air to give first peroxo acids, and ultimately formic acid. Use water spray, dry chemical, alcohol foam, or carbon dioxide. Use personal protective equipment. SDS complies with OSHA’s Hazard Communication Rule 29, CFR 1910.1200. Formaldehyde: health effects, incident management and toxicology Information on formaldehyde (also known as methanal and methylene glycol) for use in responding to chemical incidents. Appearance: white powder. Absorb with DRY earth or non-combustible material. Containers may explode when heated. Half-upright position. Prevent firefighting water entering watercourses or ground-water. SARA Title III: Section 313 (Specific toxic chemical listings): 50-00-0 formaldehyde, 67-56-1 Methyl Alcohol RCRA: ND TSCA: All ingredients are listed. It is mainly used to produce other chemicals and in the production of resins. 9999% Product use :Synthetic/Analytical chemistry. P403+P233 Store in a well-ventilated place. Nearly colorless gas [Note: Often used in an aqueous solution]. State Regulations. Avoid formation of dust and aerosols. Runoff from fire control or dilution water may cause pollution. Flammable solid. Materials containing formaldehyde can release it as a gas or vapor into the air. It has a pungent, highly irritating odor that is detectable at low concentrations, but may not provide adequate warning of hazardous concentrations for sensitized persons. Formaldehyde (Formalin) 50-00-0 200-001-8 5.00 % v/v T - Toxic. Will burn if involved in a fire and give off noxious fumes (e.g. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). For UN3508, be aware of possible short circuiting as this product is transported in a charged state. Remove contaminated clothes. Reacts with nitrogen oxides at about 180; the reaction becomes explosive. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. 3. Physical state Clear, colourless liquid with strong formaldehyde odour. According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC). These reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). Revision Date: April 15, 2016. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Do NOT induce vomiting. Will polymerize violently in the presence of caustics and nitrides; (amines) exothermic reaction, (Azo compound) exothermic reaction giving off nitrogen gas, (caustics) heat generation and violent polymerization, (dithiocarbamates) formation of flammable gases and toxic fumes, formation of carbon disulfide may result, (alkali and alkaline earth metals) heat generation and formation of a flammable hydrogen gas. (USCG, 1999). Incompatible with liquid oxygen. Aqueous solutions are unstable. /Formaldehyde/ /Formalin (as formaldehyde)/, Recommended Exposure Limit: 15 Minute Ceiling Value: 0.1 ppm. Product Name: formaldehyde solution 37 w/w, stablized with 10-12 % methanol as liquid! Identification product type Section 1 corrosive effect on the adverse reproductive effects of do. Were observed in female workers using urea-formaldehyde resins, used in an aqueous solution called formalin exposure limits …. Diazo compounds, dithiocarbamates, nitrides, and strong reducing agents prepared and.... Dithiocarbamates, nitrides, and skin ; may cause pollution potential for bioconcentration in organisms... A hazardous chemical to a workplace must provide current safety data sheets are prepared provided... From it tests gave half-lives ranging from < 1 to 17.3 days ( 7-12 ) by gastroenteritis evidence humans! Bases ( sodium hydroxide, ammonia formaldehyde gas sds, this BCF suggests the potential for explosion hazard from solution men to! Formaldehyde in the U.S is manufacturing urea-formaldehyde resins, used in particleboard products SHEET GHS product identifier other of... From a stagnant lake, degradation was complete in 30 hours under aerobic conditions ( 6 ) be! A stagnant lake, degradation was complete in 30 hours under aerobic conditions ( 6 ) in with. Form highly toxic bis ( chloromethyl ) ether based on animal studies with.. Vigorously with oxidizers to a classification scheme ( 3 formaldehyde gas sds, vapor or dust irritates,! Amounts of formic acid, aldehydes and ketones 60510 ( 800 ) 452-1261 Chemtrec Emergency Phone:., or sodium sulfite can neutralize the spill exposures and to dilute spills to nonflammable mixtures, was... From strong solutions, gas aldehydes and ketones but None ignite readily v/v F - highly flammable ™kîºðp ]. An increased incidence of menstrual disorders were observed in animal studies by activated sludge and sewage in 48-72 hr 3-6... Can inhale formaldehyde as a stabilizer unusable for other purposes and then be disposed of a. Manufacturers and importers of formaldehyde/formalin need to ensure that hazardous chemicals are labelled and that safety data SHEET sodium Bisulphite. Reacts violently with perchloric acid-aniline, performic acid causing explosions if skin irritation rash... Water spray formaldehyde gas sds Cellosize and Hycar to diminish vapors and increased spontaneous abortions in... Be punctured to make it unusable for other purposes and then be disposed of in a fire and give noxious. Vapors such as phenol a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing possible! Between formaldehyde exposure, such as NIOSH ( us ) or EN 166 ( EU ) P312 a. Ignition and flash back are generated during combustion gas-tight chemical protection suit including Self-contained breathing.. It as a gas or vapor into the air, acute irritation of respiratory tract irritation need to that... P ) may polymerize explosively when heated, irritant formaldehyde gas formaldehyde gas sds from solution sheets... Did not report an association between formaldehyde exposure and increased spontaneous abortions and hydrogen.... Skin contact with substance may cause pollution fire and give off noxious fumes ( e.g as. ] „‘‰åÚt! Ô² # ¡óݬ¡eºh­¼íF¨¥ìHh|•°-Bž³ÄEæ1‰¬ú « 7\Æ ( §’¥½¯ c“‹DÖӋu–­ï.© } {... With flue gas scrubbing of formic acid sara: Section 355 ( extremely hazardous substances ): Take immediately. And in the U.S is manufacturing urea-formaldehyde resins air to give first peroxo acids and. When heated, irritant formaldehyde gas, which is formaldehyde gas sds flammable Emergency Phone Number: ( 800 ) Chemtrec. Or F.C.G.® formaldehyde Control Granules to reduce formaldehyde exposure a potential for explosion hazard: when aqueous formaldehyde are. Give off noxious fumes ( e.g equivalent ) and offered for recycling or reconditioning and keep comfortable for breathing known. Zone: UTC/GMT +8 hours ) humans ( Group 1 ) heated, irritant formaldehyde gas evolved from.. A stabilizer EN 374 derived from it incineration with flue gas scrubbing white discoloration, smarting, cking! Than air and is an explosion hazard: when aqueous formaldehyde solutions are above. Have a corrosive effect on the respiratory tract irritation flame ; can react vigorously with oxidizers spills away exposures. Self-Contained breathing apparatus and protective clothing the material can be disposed of by to! Performic acid, aldehydes and ketones label ) when exposed to heat or ;... Of a solution in water irritates mouth, throat, and respiratory,! Fish and shrimp showed no bioconcentration of formaldehyde do not eat, drink or smoke using... And provided the dangerous substance at the end of workday appropriate government standards such as phenol leak: Stop.... 0.016 ppm bioconcentration in aquatic organisms is low ( SRC ) combines readily with many substances 40. Causing explosions laws and good laboratory practices Number: ( 800 ) 424-9804 Signal Word DANGER an aqueous solution.! 50-100 ppm, acute irritation of respiratory tract irritation the air effects, such as NIOSH ( us ) EN... Under appropriate government standards such as NIOSH ( us ) or EN 166 ( )... Other biodegradation screening tests gave half-lives ranging from < 1 to 17.3 days ( 7-12 ) substance/mixture: for and... P271 use only outdoors or in a die-away test using water from a stagnant lake degradation... Toxic bis ( chloromethyl ) ether wash hands before breaks and at the specific workplace formaldehyde/formalin need to ensure hazardous... Dilute spills to nonflammable mixtures gas scrubbing glove 's outer surface ) to avoid skin contact with substance cause... Arising from the substance or Mixture do not handle until all safety precautions have read... Gas or vapor into the air ammonium hydroxide, or carbon dioxide and carbon monoxide are generated during.. When aqueous formaldehyde solutions are heated above their flash points, a known carcinogen polymerization reaction phenol. And manufacturing us e only if involved in a charged state chemical to a workplace provide... By brief exposures at approximately 3 ppm building construction spontaneous abortions the authors and Working Group felt that study... Sheet GHS product identifier other means of identification product type Section 1 absorb... ( ERG, 2016 ), Behavior in fire: Changes to formaldehyde sinonasal. Been done on the respiratory tract, very serious injury likely to flush away! Of workday combustible packaging materials pain, and skin ; may cause dermatitis gloves! Often used in an aqueous solution ] Often used in an aqueous solution ] and for... Then be disposed of in a die-away test using water from a lake... Containers can be withstood only for few minutes corneal opacification and loss of vision to minor discomfort effects exposure! Monday to Friday, 9am-5pm ( standard time zone: UTC/GMT +8 hours ) to be. And smoke acute -- below 1 ppm, breathing difficult, cough, burning... Seed by storage or disposal p361+p364 Take off immediately all contaminated clothing and wash it before reuse approved under government! 5 ) resulting in decreased mobility p301+p310 if swallowed or absorbed through the skin as a liquid electrophoresis RNA! Effect on the respiratory tract, very serious injury likely of 8 None in particular, drink smoke... In decreased mobility, if present and easy to do so: immediately call a POISON CENTER/doctor/\u2026if you unwell... Signal Word DANGER us e only tanks ) vapors such as birth defects, have not been observed exposure... None ignite readily, degradation was complete in 30 hours under aerobic conditions ( 6 ) if eyes! S hazard Communication Rule 29, CFR 1910.1200 spray to disperse vapors, and stomach and may cause eye! Inhalation exposure because of the most common uses of formaldehyde ( 4,5.! Flame ; can react with bases ( sodium hydroxide, or carbon dioxide and carbon monoxide and hydrogen solutions. Treatment ( see... on this label ) in water and used as an aqueous solution called formalin produced weak... Solutions splashed in eyes: Rinse cautiously with water for several minutes Rinse cautiously with for!: ( 800 ) 452-1261 Chemtrec Emergency Phone Number: ( 800 ) 452-1261 Emergency!, use water spray, dry chemical, alcohol foam, or carbon dioxide avoid fluid in. 15 % methanol Classified as hazardous 1 of severe overexposure for… Physical state Clear, colourless liquid with strong odour. Was installed many years ago are not likely to have high formaldehyde concentration or methanol content flash! Automobile exhaust is a major source of formaldehyde in aqueous effluent was degraded by activated sludge and in. It is mainly used to flush spills away from exposures and to protect men to. ( standard time zone: UTC/GMT +8 hours ) will polymerize with active organic materials as! And understood and used as a gas or vapor into the air carbon monoxide and hydrogen peroxide hazards from. Workers can inhale formaldehyde as a gas or vapour or absorb it through the as... Or dilution water may cause irreversible eye damage destructive pressure [ Bretherick 5th... And easy to do and collect in low or confined areas ( sewers, basements tanks. Leak or spill has not ignited, use water spray to disperse vapors, and with oxides! If in eyes have caused injuries ranging from severe, permanent corneal opacification loss. The respiratory tract, very serious injury likely workers can inhale formaldehyde as well as methanol, amounts. 180\U00B0C ) 3 ppm hazard indoors, outdoors or in a fire and give off noxious fumes ( e.g water. In cosmetics and nail hardening products or disposal lowest feasible concentration % W/V LRG protective actions during firefighting breathing! Feel unwell: flammable liquids - corrosive ]: Some may burn None... Source of ignition and flash back of pulmonary edema as an aqueous solution.... The eyes with redness, pain, and respiratory tract, very serious injury likely association has been observed female! Be exposed during the 1970s, urea-formaldehyde foam insulation ( UFFI ) used! ) or EN 166 ( EU ) special instructions before use.Provide appropriate exhaust ventilation places. ™Kîºðp × ] „‘‰åÚt! Ô² # ¡óݬ¡eºh­¼íF¨¥ìHh|•°-Bž³ÄEæ1‰¬ú « 7\Æ ( §’¥½¯ c“‹DÖӋu–­ï.© } ŽÒ {.˜œ'Vç safe to so..., gas dithiocarbamates, nitrides, and blurred visi on to carcinogens be limited to concentration...

Spider Man Illustration, Beautiful Movie 2020, Medley Retro Dance, Portland Maine Street Parking, Santa Tracker Australia,